Direct probing of ion pair formation using a symmetric triangulenium dye

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Direct probing of ion pair formation using a symmetric triangulenium dye.

The 2,6,10-tris(dialkylamino)trioxatriangulenium dyes (ATOTA(+)) are highly stabilised cationic chromophores with D(3h) symmetry. The symmetry gives rise to a degeneracy of the main electronic transition. In low polarity solvents significant splitting of this degenerate transition is observed and assigned to ion pair formation. Ion pairing of the 2,6,10-tris(dioctylamino)trioxatriangulenium ion...

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ژورنال

عنوان ژورنال: Photochemical & Photobiological Sciences

سال: 2011

ISSN: 1474-905X,1474-9092

DOI: 10.1039/c1pp05253e